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Quick Details

4A Molecular Sieve, is an alkali alumina silicate. It is the sodium form of the type A crystal structure. It has an effective pore opening of about 4 angstroms(0.4nm). It will adsorb most molecules with a kinetic diameter of less than 4 angstroms and exclude those larger.

Key Features of 4A Molecular Sieve

  1. Pore Size:

    • 4-angstrom pore size, suitable for adsorbing small molecules like water, carbon dioxide, and small hydrocarbons.

  2. High Adsorption Capacity:

    • Can adsorb up to 20-22% of its weight in water and other small molecules.

  3. Selective Adsorption:

    • Adsorbs molecules based on size and polarity, making it ideal for specific separation and drying applications.

  4. Thermal Stability:

    • Stable at high temperatures (up to 350°C), allowing for regeneration and reuse.

  5. Chemical Resistance:

    • Resistant to most chemicals, except strong acids and bases.

  6. Regenerability:

    • Can be regenerated by heating or pressure swing adsorption (PSA) processes.



Applications of 4A Molecular Sieve

  1. Drying:

    • Used to dry gases and liquids, such as natural gas, refrigerants, solvents, and hydrocarbons.

  2. Purification:

    • Removes water, carbon dioxide (CO₂), and other impurities from gas and liquid streams.

  3. Air Separation:

    • Used in air drying systems to remove moisture and CO₂.

  4. Petrochemical Industry:

    • Purifies olefins, paraffins, and other hydrocarbons.

  5. Refrigerant Drying:

    • Dries refrigerants in air conditioning and refrigeration systems.

  6. Insulated Glass Windows:

    • Used as a desiccant in double-pane windows to prevent fogging and moisture buildup.

  7. Ethanol Dehydration:

    • Removes water from ethanol to produce fuel-grade ethanol.



Advantages of 4A Molecular Sieve

  • High Efficiency:

    • Effectively removes water and small molecules from gas and liquid streams.

  • Selective Adsorption:

    • Adsorbs molecules smaller than 4 angstroms while excluding larger ones.

  • Regenerability:

    • Can be reused multiple times, reducing operational costs.

  • Thermal Stability:

    • Maintains performance at high temperatures.

  • Cost-Effective:

    • Provides long service life and low maintenance requirements.


How 4A Molecular Sieve Works

  1. Adsorption:

    • Molecules smaller than the pore size (e.g., water, CO₂) are adsorbed onto the surface of the sieve.

  2. Separation:

    • Larger molecules are excluded, allowing for selective separation of gases or liquids.

  3. Regeneration:

    • Adsorbed molecules are removed by heating (thermal regeneration) or reducing pressure (PSA), restoring the sieve's adsorption capacity.

Comparison with Other Molecular Sieves

Property4A Molecular Sieve3A Molecular Sieve5A Molecular Sieve
Pore Size4 angstroms3 angstroms5 angstroms
Adsorption CapacityHighHighModerate
ApplicationsDrying, purification, gas separationDrying of polar liquids (e.g., ethanol)Gas separation, drying
RegenerationThermal, PSAThermal, PSAThermal, PSA
CostModerateLow to moderateModerate

Regeneration Methods

  1. Thermal Regeneration:

    • The sieve is heated to 200-350°C to desorb trapped molecules.

  2. Pressure Swing Adsorption (PSA):

    • The pressure is reduced to release adsorbed gases.

  3. Vacuum Swing Adsorption (VSA):

    • A vacuum is applied to regenerate the sieve.

Technical specification

Name
Zeolite 4A
Other name
Molecular Sieve 4A
Cas No.
1344-00-9
MF
Na₁₂[(AlO₂)₁₂(SiO₂)₁₂]·nH₂O
Shape/Appearance
Granular;Pellet
Aperture
Color
Light Brown, Light Yellow, Light Pink
Product number
ZC412
ZC428
ZC435
ZC437
ZC441
Sizes
Φ0.5~1.0
(mm)
Φ1.6~2.5
(mm)
Φ3~5
(mm)
Φ4~6
(mm)
1/16
(inch)

8 × 12 (mesh)
4 × 8
 (mesh)


Crushing Strength(N/Piece)
N/A
≥ 30
≥ 70
≥ 70
≥ 45
Static H₂O adsorption capacity(75%RH,25℃)
≥ 18 (10%RH)
≥ 21.5 (50%RH)
≥ 18 (10%RH)
≥ 20 (50%RH)
≥ 20 (50%RH)
Bulk density
≥0.69g/cm²
≥0.69g/cm²
≥0.69g/cm²
≥0.69g/cm²
≥ 0.65/cm²
H₂O content (wt%)
≤1.5
≤1.5
≤1.5
≤1.5
≤1.5




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